Product ID:PHILLYCLAD 5066A HARDENER
MSDS Date:10/09/1998
FSC:8040
NIIN:01-446-0912
Status Code:A
MSDS Number: CLLKY

ITW PHILADELPHIA RESINS CORPORATION

130 COMMERCE DR.
MONTGOMERYVILLE, PA 18936
US

Emergency Phone: 800-424-9300

Info Phone: 215-855-8450

Preparer: ERNEST CARTER

Cage: 0SFY9

ITW PHILADELPHIA RESINS CORPORATION

MONTGOMERYVILLE, PA 18936 US

Telephone: 215-855-8450

Cage: 0SFY9

TRIETHYLENETETRAMINE

CAS: 112-24-3

RTECS: YE6650000

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

DIMER/TOFA, REACTION PRODUCTS WITH TETA

CAS: 68082-29-1

LD50 LC50 Mixture:NONE
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Health Hazards Acute and Chronic:HAZARDS: SEVERE EYE, SKIN AND
RESPIRATORY TRACT IRRITANT (EVIDENCED BY RASH, BURNING SENSATION,
SORE THROAT, NAUSEA, SHORTNESS OF BREATH). HARMFUL IF ABSORBED
THROUGH SKIN. MAY CAUSE SKIN SENSITIZATIO N. AVOID BREATHING
VAPORS. USE WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. WASH
THOROUGHLY AFTER HANDLING. DO NOT EXPOSE TO HEAT OR FLAMES.
Effects of Overexposure:SKIN: SEVERE IRRITANT. EYES: SEVERE IRRITANT.
INHALATION: IRRITATION OF NOSE AND THROAT, NAUSEA AND VOMITING IN
SEVERE CASES. INGESTION: MAY CAUSE IRRITATION OF MOUTH AND THROAT
AND GASTROINTESTINAL T RACT. REPEATED SKIN CONTACT CAN CAUSE
SENSITIZATION, WITH ITCHING, RASHES, OR SWELLING OF THE SKIN.
Medical Cond Aggravated by Exposure:EYE DISEASE,SKIN DISORDERS AND
ALLERGIES.

First Aid:EYES:IMMEDIATELY FLUSH WITH CLEAN WATER FOR AT LEAST 15
MINUTES WHILE GENTLY HOLDING EYELIDS OPEN. SKIN: WASH WELL WITH
SOAP AND WARM WATER. SEE A DOCTOR. INHALATION: REMOVE PATIENT TO
FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. SEE
DOCTOR. INGESTION: DO NOT INDUCE VOMITING. DILUTE WITH LOTS OF MILK
OR WATER AND GET IMMEDIATE MEDICAL HELP.

Flash Point Method:TCC
Flash Point:=93.3C, 200.F
Extinguishing Media:WATER CARBON DIOXIDE DRY CHEMICAL.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF CONTAINED
BREATHING APPARATUS AND SUFFICIENT PROTECTIVE GEAR TO PREVENT ALL
SKIN AND EYE CONTACT WITH THIS MATERIAL.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:FOR LARGE SPILLS, PUMP TO STORAGE/SALVAGE
VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND, OR
OTHER SUITABLE MATERIAL AND DISPOSE OF PROPERLY. FLUSH AREA WITH
WATER TO REMOVE TRACE RESID UE.

Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES, OR
CLOTHING. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLE MIXED
RESIN HARDENER IN ACCORDANCE WITH THE POTENTIAL HAZARD OF THE
CURING AGENT . STORE IN A COOL, DRY ARE A.

Respiratory Protection:NONE NEEDED IN NORMAL USE WITH PROPER
VENTILATION. IN POORLY VENTILATED AREAS OR WHEN CREATING A DUST OR
MIST, USE NIOSH APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:GENERAL MECHANICAL VENTILATION IS ADEQUATE FOR OCCASIONAL
USE. FOR PROLONGED OR REPEATED USE, LOCAL EXHAUST IS RECOMMENDED.
Protective Gloves:CHEMICAL RESISTANT RUBBER GLOVES.
Eye Protection:SAFETY GLASSES WITH SIDESHIELDS OR CHEMICAL GOGGLES.
Other Protective Equipment:NONE
Work Hygienic Practices:NONE
Supplemental Safety and Health
HAVE EMERGENCY SHOWER AND EYE WAH STATIONS AVAILABLE.

Boiling Pt:=232.2C, 450.F
Vapor Pres:(MMHG): <0.01 AT 68 F
Vapor Density:AIR=1 >1
Spec Gravity:1-1.5
pH:ALKALINE
Evaporation Rate & Reference:(BUTYL ACETATE=1): <<1

STRONG OXIDIZERS, ACIDS, CHLORINATED ORGANIC COMPOUNDS.
Stability Condition to Avoid:EXTREME HEAT OR OPEN FLAME.
Hazardous Decomposition Products:FIRE: ACRID AND TOXIC FUMES WITH
ORGANIC AMINES, AMMONIA, OXIDES OF CARBON AND NITROGEN.
Conditions to Avoid Polymerization:HEAT IS RELEASED WHEN THIS PRODUCT
IS MIXED WITH EPOXY RESINS; USE CARE WHEN MIXING LARGE QUANTITIES.

Waste Disposal Methods:IF THIS MATERIAL BECOMES A WASTE, IT WOULD NOT
BE A HAZARDOUS WASTE BY RCRA CRITERIA (40CFR 261). DISPOSE OF
ACCORDING TO APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.

Toxicological Information:NOT PROVIDED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT PROVIDED.

Transport Information:COMPOUNDS, CLEANING LIQUID

Federal Regulatory Information:ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY.